We want the least integer value of \(a\) such that
\[ x^4 - ax^2 + 9 = 0 \]
has four real and distinct roots.
Put \(y=x^2\) (so \(y \ge 0\)). Then the equation becomes
\[ y^2 - ay + 9 = 0. \]
For \(x\) to have four real and distinct roots, this quadratic in \(y\) must have two distinct positive roots \(y_1, y_2\) (so that \(x=\pm\sqrt{y_1}, \pm\sqrt{y_2}\)).
Combining: \(a > 6\). Hence the least integer value is
\(a = 7\).
What will be the equilibrium constant of the given reaction carried out in a \(5 \,L\) vessel and having equilibrium amounts of \(A_2\) and \(A\) as \(0.5\) mole and \(2 \times 10^{-6}\) mole respectively?
The reaction : \(A_2 \rightleftharpoons 2A\)