Step 1: Substitute $x^2=t$.
\[ t^2-at+9=0 \] Step 2: Condition for real and distinct roots.
Discriminant must be positive: \[ a^2-36>0 \Rightarrow a>6 \] Step 3: Roots of $t$ must be positive.
Product of roots $=9>0$ and sum $=a>0$, so both roots are positive.
Step 4: Smallest integer satisfying the condition.
\[ a>6 \Rightarrow a_{\min}=7 \]
What will be the equilibrium constant of the given reaction carried out in a \(5 \,L\) vessel and having equilibrium amounts of \(A_2\) and \(A\) as \(0.5\) mole and \(2 \times 10^{-6}\) mole respectively?
The reaction : \(A_2 \rightleftharpoons 2A\)