Step 1: Understanding the electric field.
The electric field \( E \) between the plates of a capacitor is given by the formula:
\[
E = \frac{V}{d}
\]
where:
- \( V \) is the voltage across the plates,
- \( d \) is the distance between the plates.
Step 2: Applying the change in voltage.
If the capacitor is connected to a battery with a voltage \( E \) across the plates, and the charge on the capacitor is \( 2q \), the electric field will double.
Step 3: Conclusion.
The electric field will become \( 2E \), so the correct answer is (C).