Solution:
We will use Newton's Law of Cooling. $$ \frac{dT}{dt} = -k(T - T_s) $$ where:
$T$ is the temperature of the object at time $t$
$T_s$ is the temperature of the surroundings
$k$ is a positive constant
Cooling from $80^{\circ}C$ to $60^{\circ}C$:
Initial temperature $T_1 = 80^{\circ}C$
Final temperature $T_2 = 60^{\circ}C$
Time $t_1 = 5 \text{ minutes} = 300 \text{ seconds}$
Surrounding temperature $T_s = 20^{\circ}C$
Using the average temperature: $$ \frac{T_1 + T_2}{2} = \frac{80 + 60}{2} = 70^{\circ}C $$ Applying Newton's Law: $$ \frac{T_2 - T_1}{t_1} = -k\left(\frac{T_1 + T_2}{2} - T_s\right) $$ $$ \frac{60 - 80}{300} = -k(70 - 20) $$ $$ \frac{-20}{300} = -k(50) $$ $$ k = \frac{20}{300 \cdot 50} = \frac{2}{1500} = \frac{1}{750} $$ Cooling from $60^{\circ}C$ to $40^{\circ}C$:
Initial temperature $T_1 = 60^{\circ}C$
Final temperature $T_2 = 40^{\circ}C$
Time $t_2$ (to be found)
Surrounding temperature $T_s = 20^{\circ}C$
Using the average temperature: $$ \frac{60 + 40}{2} = 50^{\circ}C $$ Applying Newton's Law: $$ \frac{40 - 60}{t_2} = -k(50 - 20) $$ $$ \frac{-20}{t_2} = -k(30) $$ $$ t_2 = \frac{20}{k \cdot 30} = \frac{20}{\frac{1}{750} \cdot 30} = \frac{20 \cdot 750}{30} = 20 \cdot 25 = 500 \text{ seconds} $$ Therefore, the time it takes to cool from $60^{\circ}C$ to $40^{\circ}C$ is 500 seconds.
The correct answer is (1) 500 s.
A black body is at a temperature of 2880 K. The energy of radiation emitted by this body with wavelength between 499 nm and 500 nm is U1, between 999 nm and 1000 nm is U2 and between 1499 nm and 1500 nm is U3. The Wien's constant, b = 2.88×106 nm-K. Then,

What will be the equilibrium constant of the given reaction carried out in a \(5 \,L\) vessel and having equilibrium amounts of \(A_2\) and \(A\) as \(0.5\) mole and \(2 \times 10^{-6}\) mole respectively?
The reaction : \(A_2 \rightleftharpoons 2A\)
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