Concept:
Mineral deficiencies produce characteristic symptoms in plants.
Step 1: Check each pair.
Whiptail in cauliflower \(\rightarrow\) Zinc deficiency \(\checkmark\)
Heart rot in beet \(\rightarrow\) Boron deficiency \(\checkmark\)
Mouse ear in pecan \(\rightarrow\) Nickel deficiency \(\checkmark\)
Step 2: Analyze Die-back.
Die-back of citrus is associated mainly with zinc deficiency and not copper.
Therefore pair (A) is incorrect.
\[
\boxed{\text{Option (A)}}
\]