Step 1: DPT (diphtheria, pertussis, tetanus) is an adsorbed vaccine. Adsorbed vaccines must never be frozen, because freezing damages the antigen-adjuvant complex and causes loss of potency.
Step 2: The correct storage condition is refrigeration between 4 and 8 degree C, so option b is right.
Step 3: Room temperature (option a) is too warm and accelerates loss of potency. Sub-zero storage of 0 to -20 degree C (option c) is meant for highly heat-sensitive vaccines such as oral polio vaccine at the higher levels of the cold chain, but it would freeze and destroy DPT.