Concept:
White blood cells have different functions in immunity, allergy, inflammation, and defense.
Step 1: Understanding basophils.
Basophils are granulocytic white blood cells. Their granules contain biologically active substances.
Step 2: Substances released by basophils.
Basophils release histamine and heparin. Histamine is involved in allergic reactions, while heparin acts as an anticoagulant.
Step 3: Function of heparin.
Heparin prevents blood clotting by inhibiting clot formation.
Step 4: Checking other options.
Neutrophils are mainly phagocytic.
Eosinophils are involved in allergy and parasitic infections.
Platelets help in clot formation.
Basophils secrete heparin.
\[
\boxed{\text{Basophils}}
\]