Step 1: Understanding the Concept:
Sodic (alkali) soils are salt-affected soils characterized by an excess of exchangeable sodium ions (\(\text{Na}^+\)) on the soil colloid exchange complex, leading to poor physical structure and high pH.
Step 2: Detailed Explanation:
Let us analyze both statements systematically:
- Statement (I):
The major problem in sodic soils is the excess of exchangeable sodium (\(\text{Na}^+\)), which causes clay dispersion, clogs soil pores, and elevates pH (> 8.5).
Sulphur is not a problem in these soils; in fact, elemental sulphur or gypsum (calcium sulphate, \(\text{CaSO}_4 \cdot 2\text{H}_2\text{O}\)) is added as an amendment to reclaim sodic soils by supplying calcium to displace exchangeable sodium.
Therefore, Statement (I) is incorrect.
- Statement (II):
According to the diagnostic criteria established by the United States Salinity Laboratory (USSL), sodic soils are characterized by:
1. Exchangeable Sodium Percentage (ESP) \(>\) 15%.
2. Electrical conductivity of the saturation extract (\(\text{EC}_e\)) \(<\) 4 dS \(\text{m}^{-1}\).
3. Sodium Adsorption Ratio (SAR) of the saturation extract \(\ge\) 13.
Therefore, Statement (II) is correct.
Thus, Statement (I) is incorrect but Statement (II) is correct.
Step 3: Final Answer:
The correct option is (D), as Statement (I) is incorrect and Statement (II) is correct.