Step 1: Understand the problem.
A web server receives thousands of requests, but it can only process a limited number (100 in this case) at a time. Other requests must wait in line.
Step 2: Properties of data structures.
- Stack: LIFO structure, unsuitable for fair processing of multiple requests.
- Queue: FIFO structure, ensures requests are handled in the order they arrive.
- List: General collection, but no enforced order for processing requests.
- Dictionary: Key-value mapping, not suitable for request scheduling.
Step 3: Best fit.
Since requests must be processed in arrival order, a Queue is the most appropriate data structure.
Final Answer:
\[
\boxed{\text{Queue}}
\]