$\gamma_A$ is the specific heat ratio of monoatomic gas A having 3 translational degrees of freedom. $\gamma_B$ is the specific heat ratio of polyatomic gas B having 3 translational, 3 rotational degrees of freedom and 1 vibrational mode. If \[ \frac{\gamma_A}{\gamma_B} = \left( 1 + \frac{1}{n} \right) \] then the value of \( n \) is ___.
The problem asks to find the value of \( n \) from the given relation \( \frac{\gamma_A}{\gamma_B} = \left( 1 + \frac{1}{n} \right) \), where \( \gamma_A \) and \( \gamma_B \) are the specific heat ratios for a monoatomic gas A and a polyatomic gas B, respectively, with their degrees of freedom specified.
The specific heat ratio (or adiabatic index), \( \gamma \), of a gas is related to its total degrees of freedom, \( f \), by the formula:
\[ \gamma = 1 + \frac{2}{f} \]
The total degrees of freedom (\( f \)) is the sum of translational, rotational, and vibrational degrees of freedom.
Step 1: Calculate the degrees of freedom for the monoatomic gas A (\( f_A \)).
A monoatomic gas has only translational motion. It is given that there are 3 translational degrees of freedom.
\[ f_A = f_{\text{trans}} = 3 \]
Step 2: Calculate the specific heat ratio for gas A (\( \gamma_A \)).
Using the formula for \( \gamma \):
\[ \gamma_A = 1 + \frac{2}{f_A} = 1 + \frac{2}{3} = \frac{3+2}{3} = \frac{5}{3} \]
Step 3: Calculate the degrees of freedom for the polyatomic gas B (\( f_B \)).
Gas B has 3 translational, 3 rotational, and 1 vibrational mode. As each vibrational mode corresponds to 2 degrees of freedom:
\[ f_B = f_{\text{trans}} + f_{\text{rot}} + f_{\text{vib}} \] \[ f_B = 3 + 3 + (1 \times 2) = 8 \]
Step 4: Calculate the specific heat ratio for gas B (\( \gamma_B \)).
Using the formula for \( \gamma \):
\[ \gamma_B = 1 + \frac{2}{f_B} = 1 + \frac{2}{8} = 1 + \frac{1}{4} = \frac{4+1}{4} = \frac{5}{4} \]
Step 5: Use the given relation to find the value of \( n \).
The relation is:
\[ \frac{\gamma_A}{\gamma_B} = 1 + \frac{1}{n} \]
Substitute the calculated values of \( \gamma_A \) and \( \gamma_B \):
\[ \frac{5/3}{5/4} = 1 + \frac{1}{n} \] \[ \frac{5}{3} \times \frac{4}{5} = 1 + \frac{1}{n} \] \[ \frac{4}{3} = 1 + \frac{1}{n} \]
Step 6: Solve for \( n \).
\[ \frac{1}{n} = \frac{4}{3} - 1 \] \[ \frac{1}{n} = \frac{4 - 3}{3} = \frac{1}{3} \] \[ n = 3 \]
The value of \( n \) is 3.
A black body is at a temperature of 2880 K. The energy of radiation emitted by this body with wavelength between 499 nm and 500 nm is U1, between 999 nm and 1000 nm is U2 and between 1499 nm and 1500 nm is U3. The Wien's constant, b = 2.88×106 nm-K. Then,


What will be the equilibrium constant of the given reaction carried out in a \(5 \,L\) vessel and having equilibrium amounts of \(A_2\) and \(A\) as \(0.5\) mole and \(2 \times 10^{-6}\) mole respectively?
The reaction : \(A_2 \rightleftharpoons 2A\)