Following chromatogram was developed by adsorption of compound 'A' on a 6 cm TLC glass plate. Retardation factor of the compound 'A' is_____ \(\times 10^{–1}\).
For Rf calculations:
• Measure the distances accurately for the solute and solvent front.
• Ensure the units for both distances are consistent.
• Multiply the calculated Rf value by 10−1 if required.
1. Retardation Factor (\(R_f\)):
The \(R_f\) value is defined as:
\[R_f = \frac{\text{Distance traveled by the solute (A)}}{\text{Distance traveled by the solvent front}}.\]
2. Given Data:
Total length of the TLC plate = 6 cm.
Let the solute travel 3.6 cm and the solvent front travel 6 cm.
3. Calculate \(R_f\):
\[R_f = \frac{3.6}{6} = 0.6.\]
4.Convert to \(10^{-1}\) Factor:
\[R_f \times 10^{-1} = 6 \times 10^{-1}.\]
Final Answer: \(0.6\).
The correct order of the rate of reaction of the following reactants with nucleophile by \( \mathrm{S_N1} \) mechanism is:
(Given: Structures I and II are rigid) 
A substance 'X' (1.5 g) dissolved in 150 g of a solvent 'Y' (molar mass = 300 g mol$^{-1}$) led to an elevation of the boiling point by 0.5 K. The relative lowering in the vapour pressure of the solvent 'Y' is $____________ \(\times 10^{-2}\). (nearest integer)
[Given : $K_{b}$ of the solvent = 5.0 K kg mol$^{-1}$]
Assume the solution to be dilute and no association or dissociation of X takes place in solution.
Inductance of a coil with \(10^4\) turns is \(10\,\text{mH}\) and it is connected to a DC source of \(10\,\text{V}\) with internal resistance \(10\,\Omega\). The energy density in the inductor when the current reaches \( \left(\frac{1}{e}\right) \) of its maximum value is \[ \alpha \pi \times \frac{1}{e^2}\ \text{J m}^{-3}. \] The value of \( \alpha \) is _________.
\[ (\mu_0 = 4\pi \times 10^{-7}\ \text{TmA}^{-1}) \]