Question

Fluorine differs from other halogens in some of its properties. This is due to

• A. Its smaller size and high electronegativity
• B. Lack of d-orbitals
• C. Low bond dissociation energy
• D. All of the these

Answer 1

The Correct Option is D

Fluorine differs from other halogens due to several unique characteristics:

• Smaller Size and High Electronegativity: Fluorine is the smallest halogen, leading to a high electron density around its nucleus. This contributes to its extremely high electronegativity, making it the most electronegative element in the periodic table.
• Lack of d-Orbitals: Fluorine does not have d-orbitals in its valence shell, which limits its ability to expand its octet and participate in certain chemical reactions compared to heavier halogens that can use d-orbitals.
• Low Bond Dissociation Energy: The bond dissociation energy of the F-F bond is low due to the small size of the fluorine atom causing repulsion between non-bonded electrons of the two fluorine atoms when bonded, making the bond weaker.

Thus, these properties: smaller size, high electronegativity, lack of d-orbitals, and low bond dissociation energy, together, differentiate fluorine from other halogens.

Therefore, the correct answer is: All of the these.