Step 1: Recall the formula for the angle between two vectors
If \(\vec{a}\) and \(\vec{b}\) are two vectors, then the angle \(\theta\) between them is given by:
\[
\cos \theta = \frac{\vec{a} \cdot \vec{b}}{|\vec{a}| \, |\vec{b}|}
\]
Step 2: Identify the vectors
\[
\vec{a} = -2\hat{i} + \hat{j} + 3\hat{k}
\]
\[
\vec{b} = 3\hat{i} - 2\hat{j} + \hat{k}
\]
Step 3: Calculate the dot product \(\vec{a} \cdot \vec{b}\)
\[
\vec{a} \cdot \vec{b} = (-2)(3) + (1)(-2) + (3)(1)
\]
\[
\vec{a} \cdot \vec{b} = -6 - 2 + 3
\]
\[
\vec{a} \cdot \vec{b} = -5
\]
Step 4: Calculate the magnitudes of \(\vec{a}\) and \(\vec{b}\)
\[
|\vec{a}| = \sqrt{(-2)^2 + (1)^2 + (3)^2} = \sqrt{4 + 1 + 9} = \sqrt{14}
\]
\[
|\vec{b}| = \sqrt{(3)^2 + (-2)^2 + (1)^2} = \sqrt{9 + 4 + 1} = \sqrt{14}
\]
Step 5: Apply the formula
\[
\cos \theta = \frac{-5}{\sqrt{14} \times \sqrt{14}} = \frac{-5}{14}
\]
Step 6: Find the angle
\[
\theta = \cos^{-1} \left( \frac{-5}{14} \right)
\]
\[
\theta = \cos^{-1} \left( -0.3571 \right) \approx 111^\circ \ (\text{approximately})
\]
Step 7: Final answer
\[
\boxed{\theta = \cos^{-1}\left(-\frac{5}{14}\right)}
\]
or approximately \(\boxed{111^\circ}\).