Step 1: Understand the concept of molarity.
Molarity is given by \( M = \frac{\text{moles}}{\text{volume in liters}} \). If equal weights of NaCl and KCl are dissolved in the same volume, the molarity will be higher for NaCl due to its lower molar mass.
Step 2: Conclusion.
The molarity of NaCl will be more than that of KCl.
Final Answer:
\[
\boxed{\text{That of NaCl will be more than that of KCl}}
\]