Step 1: Check the units of each option.
Heat exchanger effectiveness is defined as the ratio of actual heat transfer rate to the maximum possible heat transfer rate, \(\varepsilon = \dfrac{Q_{actual}}{Q_{max}}\).
Both quantities in this ratio carry units of watts, so they cancel and effectiveness is a pure number.
Step 2: Rule out the other options.
Humid heat has units of \(\text{kJ.kg}^{-1}.\text{K}^{-1}\), humid volume has units of \(\text{m}^3.\text{kg}^{-1}\), and overall heat transfer coefficient has units of \(\text{W.m}^{-2}.\text{K}^{-1}\).
None of these three cancel out to a pure number, so all three carry dimensions.
Final Answer:
Only heat exchanger effectiveness is dimensionless.
\[ \boxed{\text{heat exchanger effectiveness}} \]