Step 1: Relation of potential with charge.
For a sphere of radius $R$,
\[
V = \frac{1}{4\pi \epsilon_0} \cdot \frac{Q}{R}.
\]
If both spheres are at same potential:
\[
\frac{Q_1}{R_1} = \frac{Q_2}{R_2}.
\]
Step 2: Express $Q$ in terms of surface density.
\[
Q = \sigma \cdot 4\pi R^2.
\]
So,
\[
\frac{\sigma_1 \cdot 4\pi R_1^2}{R_1} = \frac{\sigma_2 \cdot 4\pi R_2^2}{R_2}.
\]
\[
\sigma_1 R_1 = \sigma_2 R_2.
\]
Step 3: Substitution.
$R_1 = 3 \, \text{cm}$, $R_2 = 2 \, \text{cm}$.
\[
\sigma_1 \cdot 3 = \sigma_2 \cdot 2.
\]
\[
\sigma_1 : \sigma_2 = 2 : 3.
\]
Step 4: Conclusion.
The ratio of surface charge densities is $2 : 3$.