We are given: - Molarity (M) = 3 M (mol/L) - Density of solution = 1.25 g/mL = 1250 g/L
The molality (m) is given by the formula: \[ m = \frac{\text{moles of solute}}{\text{kg of solvent}} \]
From molarity, the number of moles of NaCl in 1 liter of solution is: \[ \text{moles of NaCl} = 3 \, \text{mol} \]
To find the mass of NaCl, use the molar mass of NaCl (58.44 g/mol): \[ \text{mass of NaCl} = 3 \, \text{mol} \times 58.44 \, \text{g/mol} = 175.32 \, \text{g} \]
Now, the mass of the solvent (water) is: \[ \text{mass of solvent} = 1250 \, \text{g} - 175.32 \, \text{g} = 1074.68 \, \text{g} = 1.07468 \, \text{kg} \]
Thus, the molality is: \[ m = \frac{3 \, \text{mol}}{1.07468 \, \text{kg}} = 2.79 \, \text{m} \]
Therefore, the correct answer is 2.79 m.
What will be the equilibrium constant of the given reaction carried out in a \(5 \,L\) vessel and having equilibrium amounts of \(A_2\) and \(A\) as \(0.5\) mole and \(2 \times 10^{-6}\) mole respectively?
The reaction : \(A_2 \rightleftharpoons 2A\)

Cobalt chloride when dissolved in water forms pink colored complex $X$ which has octahedral geometry. This solution on treating with cone $HCl$ forms deep blue complex, $\underline{Y}$ which has a $\underline{Z}$ geometry $X, Y$ and $Z$, respectively, are
| Sample | Van't Haff Factor |
|---|---|
| Sample - 1 (0.1 M) | \(i_1\) |
| Sample - 2 (0.01 M) | \(i_2\) |
| Sample - 3 (0.001 M) | \(i_2\) |
What will be the equilibrium constant of the given reaction carried out in a \(5 \,L\) vessel and having equilibrium amounts of \(A_2\) and \(A\) as \(0.5\) mole and \(2 \times 10^{-6}\) mole respectively?
The reaction : \(A_2 \rightleftharpoons 2A\)