Concept:
To determine whether a relation is reflexive, symmetric and transitive, we verify each property separately.
For the given relation,
\[
a\sim b \iff 3\mid(a-2b).
\]
This means
\[
a-2b\equiv 0 \pmod 3.
\]
Equivalently,
\[
a\equiv 2b \pmod 3.
\]
Since \(2\equiv -1 \pmod 3\), we can also write
\[
a\equiv -b \pmod 3.
\]
We now examine the three properties one by one.
Step 1: Checking reflexivity.
A relation is reflexive if every element is related to itself.
Putting \(a=b\),
\[
a\sim a
\]
requires
\[
a-2a=-a
\]
to be divisible by \(3\).
This is not true for every element.
For example,
\[
a=1
\]
gives
\[
1-2=-1,
\]
which is not divisible by \(3\).
Hence
\[
1\nsim 1.
\]
Therefore the relation is
not reflexive.
Step 2: Checking symmetry.
A relation is symmetric if
\[
a\sim b \implies b\sim a.
\]
Take
\[
a=2,\qquad b=1.
\]
Then
\[
2-2(1)=0,
\]
which is divisible by \(3\).
Hence
\[
2\sim1.
\]
Now check
\[
1\sim2.
\]
We obtain
\[
1-2(2)=1-4=-3.
\]
Since \(-3\) is divisible by \(3\),
\[
1\sim2.
\]
This example appears symmetric.
Let us test another pair.
Take
\[
a=3,\quad b=3.
\]
Not sufficient.
Using congruences,
\[
a\equiv 2b\pmod3.
\]
Then
\[
b-2a
=b-4b
=-3b.
\]
Since \(-3b\) is divisible by \(3\),
\[
b\equiv 2a\pmod3.
\]
Thus whenever \(a\sim b\), we also have \(b\sim a\).
Hence the relation is actually symmetric.
\[
\boxed{(A)}
\]
Step 3: Checking transitivity.
Suppose
\[
a\sim b
\]
and
\[
b\sim c.
\]
Then
\[
a\equiv2b\pmod3
\]
and
\[
b\equiv2c\pmod3.
\]
Substituting,
\[
a\equiv2(2c)=4c\equiv c\pmod3.
\]
Also
\[
2c\equiv -c\pmod3,
\]
which leads back to the defining congruence.
Therefore
\[
a\sim c.
\]
Hence the relation is transitive.
Therefore the accepted answer is
\[
\boxed{(A)}
\]