Let us examine each statement:
[I.] False — Adjacent angles at an intersection are not necessarily complementary (sum is not always 90°).
[II.] True — Adjacent angles formed at a point of intersection sum up to 180°, so they are supplementary.
[III.] True — Vertically opposite angles formed by intersecting lines are always equal.
[IV.] False — Opposite angles are equal, but not necessarily supplementary unless each is 90°, which is not always the case.
Therefore, only (II) and (III) are correct.
\[
{\text{Statements II and III are correct}}
\]