Step 1: Analyze Statement I:
Natural rubber is a linear polymer of Isoprene (2-methyl-1,3-butadiene), specifically cis-1,4-polyisoprene.
The polymer of 2-chloro-1,3-butadiene (Chloroprene) is called Neoprene (synthetic rubber).
Therefore, Statement I is Incorrect.
Step 2: Analyze Statement II:
1,3-Butadiene-styrene copolymer is known as Buna-S (SBR - Styrene Butadiene Rubber). This is a widely used synthetic rubber.
Therefore, Statement II is Correct.
Step 3: Conclusion:
Statement I is False, Statement II is True. Matches Option (D).