Concept:
A matrix inverse, orthogonal matrix and skew-symmetric matrix have fixed standard properties.
Step 1: Check statement A.
If inverse of a matrix exists, then it is unique.
\[
A \text{ is correct}
\]
Step 2: Check statement B.
A matrix is non-singular when:
\[
|A|\neq 0
\]
But statement B says:
\[
|A|=0
\]
So B is incorrect.
Step 3: Check statement C.
For:
\[
A=\begin{pmatrix}
\cos x & \sin x
-\sin x & \cos x
\end{pmatrix}
\]
we get:
\[
AA^T=I
\]
So the matrix is orthogonal.
\[
C \text{ is correct}
\]
Step 4: Check statement D.
For a skew-symmetric matrix:
\[
a_{ij}=-a_{ji}
\]
Here:
\[
a_{23}=-4,\quad a_{32}=-4
\]
But for skew-symmetric matrix, these should be opposite in sign.
So D is incorrect.
Therefore, correct statements are:
\[
A,C
\]
\[
\therefore \text{Correct Answer is (C)}
\]