Question:

Consider the following ionization enthalpies of two elements ‘A’ and ‘B’.
ElementIonization enthalpy (kJ/mol)
1st2nd3rd
A899175714847
B73714507731
Which of the following statements is correct ?

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A very large jump after the 2nd ionization enthalpy means two valence electrons (group 2); lower IE means lower in the group.
Updated On: Nov 11, 2026
  • Both ‘A’ and ‘B’ belong to group-1 where ‘B’ comes below ‘A’.
  • Both ‘A’ and ‘B’ belong to group-1 where ‘A’ comes below ‘B’.
  • Both ‘A’ and ‘B’ belong to group-2 where ‘B’ comes below ‘A’.
  • Both ‘A’ and ‘B’ belong to group-2 where ‘A’ comes below ‘B’.
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The Correct Option is C

Solution and Explanation

For both A and B the third ionization enthalpy is much larger than the second (14847 vs 1757 and 7731 vs 1450), so the third electron is removed from a stable inner (noble-gas) core. Hence each element has 2 valence electrons: both belong to group 2 (in group 1 the big jump would come after the 1st).
Ionization enthalpy decreases down a group. A (899, 1757) has higher values than B (737, 1450), so A is above B, i.e. B comes below A (A = Be, 899.5; B = Mg, 737.7).
Answer: (3) Both ‘A’ and ‘B’ belong to group-2 where ‘B’ comes below ‘A’.
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