Question:

Concentrated \(\mathrm{HNO_3}\) used in the laboratory is \(68\%\) by mass and its density is \(1.5\ \mathrm{g\,mL^{-1}}\). If \(x\) mL of this acid was taken into a 5 L standard flask and filled up to the mark with distilled water to prepare \(5\) L of \(0.5\ \mathrm{M}\ \mathrm{HNO_3}\) solution. What is the value of \(x\) in mL?

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Use \[ \boxed{\text{Mass}=\frac{\text{Required mass of solute}}{\%\text{ by mass}/100}} \] and then \[ \boxed{\text{Volume}=\frac{\text{Mass}}{\text{Density}}.} \]
Updated On: Jul 15, 2026
  • \(15.44\)
  • \(154.4\)
  • \(1544\)
  • \(77.2\)
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The Correct Option is B

Solution and Explanation

Step 1: Calculate moles required. \[ M=\frac{n}{V} \] \[ n=0.5\times5=2.5\ \text{mol} \] Mass of pure \(\mathrm{HNO_3}\) \[ =2.5\times63=157.5\ \text{g} \]

Step 2:
Calculate mass of concentrated acid. Since acid is \(68\%\) by mass, \[ \text{Mass of solution} =\frac{157.5}{0.68} =231.6\ \text{g} \] Volume required \[ =\frac{231.6}{1.5} =154.4\ \text{mL} \] Therefore, \[ \boxed{154.4\ \text{mL}} \] Hence, \[ \boxed{(B)} \] is the correct answer.
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