Concept:
Flowering plants exhibit various outbreeding devices that prevent self-pollination and promote cross-pollination.
Step 1: Protandry -- Datura.
In protandry, anthers mature before stigma.
Datura is a common example.
Hence Pair I is correct.
Step 2: Herkogamy -- Gloriosa.
Herkogamy involves spatial separation of anthers and stigma.
Gloriosa exhibits herkogamy.
Hence Pair II is correct.
Step 3: Self sterility -- Abutilon.
Abutilon is not a standard example of self-sterility.
Therefore Pair III is incorrect.
Step 4: Protogyny -- Sunflower.
Sunflower generally shows:
\[
\boxed{\text{Protandry}}
\]
not protogyny.
Hence Pair IV is incorrect.
Thus incorrect pairs are:
\[
\boxed{\text{III and IV}}
\]
Hence option (D) is correct.