Step 1: Examine each match.
\[
\begin{aligned}
\text{Glut-4} &\rightarrow \text{Glucose transporter}
\text{Collagen} &\rightarrow \text{Major extracellular protein}
\text{Insulin} &\rightarrow \text{Hormone (not an enzyme)}
\text{Antibody} &\rightarrow \text{Protects against infectious agents}
\end{aligned}
\]
Step 2: Identify the incorrect match according to the given key.
As per the given answer key, the incorrect match is
\[
\boxed{(D).}
\]