Step 1: Understanding the Question:
We need to evaluate the correctness of four separate statements related to photons, electromagnetic waves, and de-Broglie wavelength.
Step 2: Detailed Explanation:
Statement (A):
Energy of a single photon is \(E_{ph} = \frac{hc}{\lambda}\).
The number of photons \(N\) in a beam of total energy \(E_{total}\) is \(N = \frac{E_{total}}{E_{ph}} = \frac{E_{total} \lambda}{hc}\).
Given: \(E_{total} = 1\) J, \(\lambda = 2000 \text{ pm} = 2000 \times 10^{-12}\) m.
\(h = 6.626 \times 10^{-34}\) J·s, \(c = 3 \times 10^8\) m/s.
\[ N = \frac{(1 \text{ J})(2000 \times 10^{-12} \text{ m})}{(6.626 \times 10^{-34} \text{ Js})(3 \times 10^8 \text{ m/s})} = \frac{2 \times 10^{-9}}{19.878 \times 10^{-26}} \approx 0.1006 \times 10^{17} = 1.006 \times 10^{16} \] This value is very close to \(1.01 \times 10^{16}\). Statement (A) is correct.
Statement (B):
The energy of a photon is inversely proportional to its wavelength (\(E \propto 1/\lambda\)).
Therefore, the ratio of energies is \(\frac{E_1}{E_2} = \frac{\lambda_2}{\lambda_1}\).
Given: \(\lambda_1 = 300\) nm, \(\lambda_2 = 900\) nm.
\[ \frac{E_1}{E_2} = \frac{300 \text{ nm}}{900 \text{ nm}} = 3 \] The statement claims \(\frac{E_1}{E_2} = 1/3\). Statement (B) is incorrect.
Statement (C):
The relationship between frequency (\(f\)), wavelength (\(\lambda\)), and the speed of light (\(c\)) is \(\lambda = \frac{c}{f}\).
Given: \(f = 4.5 \times 10^{16}\) Hz.
\[ \lambda = \frac{3 \times 10^8 \text{ m/s}}{4.5 \times 10^{16} \text{ Hz}} = \frac{3}{4.5} \times 10^{-8} \text{ m} = \frac{2}{3} \times 10^{-8} \text{ m} \approx 0.667 \times 10^{-8} \text{ m} = 6.67 \times 10^{-9} \text{ m} \] This value is approximately \(6.7 \times 10^{-9}\) m. Statement (C) is correct.
Statement (D):
The de-Broglie wavelength is given by \(\lambda = \frac{h}{p}\), where \(p\) is the momentum.
When a particle of charge \(q\) is accelerated by a potential difference \(V\), its kinetic energy is \(K = qV\).
Momentum is related to kinetic energy by \(p = \sqrt{2mK}\).
So, \(\lambda = \frac{h}{\sqrt{2mK}} = \frac{h}{\sqrt{2mqV}}\).
Electrons and protons have the same magnitude of charge \(q\) but different masses (\(m_p >> m_e\)). If they are accelerated by the same \(V\), their wavelengths will be different. Specifically, since mass is in the denominator, the more massive proton will have a shorter wavelength. Statement (D) is incorrect.
Step 3: Final Answer:
Statements (A) and (C) are correct, while (B) and (D) is incorrect. The best choice among the options is (C) which states A & C are correct.
A black body is at a temperature of 2880 K. The energy of radiation emitted by this body with wavelength between 499 nm and 500 nm is U1, between 999 nm and 1000 nm is U2 and between 1499 nm and 1500 nm is U3. The Wien's constant, b = 2.88×106 nm-K. Then,

What will be the equilibrium constant of the given reaction carried out in a \(5 \,L\) vessel and having equilibrium amounts of \(A_2\) and \(A\) as \(0.5\) mole and \(2 \times 10^{-6}\) mole respectively?
The reaction : \(A_2 \rightleftharpoons 2A\)