Question:

Bromine trifluoride auto ionizes into BrF\(_2^+\) and BrF\(_4^-\). The geometry of these ions respectively are:

Updated On: Apr 13, 2026
  • Linear , square planar
  • Bent , square planar
  • Bent , see-saw
  • Linear , tetrahedral
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The Correct Option is B

Solution and Explanation


Step 1: For BrF\(_2^+\) ion.

BrF\(_2^+\) ion has 2 bond pairs and 2 lone pairs, which corresponds to \( sp^3 \) hybridization. This results in a bent geometry. Therefore, the geometry of BrF\(_2^+\) is bent.
Step 2: For BrF\(_4^-\) ion.

BrF\(_4^-\) ion has 4 bond pairs and 2 lone pairs, which corresponds to \( sp^3d^2 \) hybridization. This results in a square planar geometry. Therefore, the geometry of BrF\(_4^-\) is square planar.
Step 3: Conclusion.

Hence, the correct match for the geometry of BrF\(_2^+\) and BrF\(_4^-\) is bent and square planar respectively. The correct answer is (B). Final Answer: Bent, square planar.
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