Concept:
Before senescence and leaf fall, plants remobilize several nutrients from old leaves and transport them to young growing tissues.
Elements are classified into:
• Mobile elements
• Immobile elements
Mobile nutrients can be transported from older tissues to younger tissues, whereas immobile nutrients remain fixed.
Step 1: Identify mobile nutrients.
Highly mobile nutrients include:
\[
N,\; P,\; K,\; Mg
\]
Among these, phosphorus is readily remobilized before leaf abscission.
Step 2: Identify immobile nutrients.
Calcium is largely immobile because it becomes incorporated into cell walls and other stable structures.
Once deposited, it is not easily transported to other plant parts.
Step 3: Analyze options.
Option (A):
Nickel is not considered the classic immobile nutrient in this context.
Incorrect.
Option (B):
Sulphur shows limited mobility.
Incorrect combination.
Option (C):
Both phosphorus and potassium are mobile.
Incorrect.
Option (D):
Phosphorus is mobile and calcium is immobile.
Correct.
Step 4: Final conclusion.
The correct pair is:
\[
\boxed{\text{Phosphorus and Calcium}}
\]
Hence option (D) is correct.