$\sin^{-1} \left( -\frac{5}{6} \right)$
To solve this problem, we need to clearly understand the concept of the critical angle and how it relates to the refractive indices of the materials involved:
We are tasked with solving for the critical angles $ \theta_{1C} $ and $ \theta_{2C} $, and determining the relationship between the refractive indices $ n_1 $, $ n_2 $, and $ n_3 $. The solution proceeds as follows:
1. Critical Angle Relations:
The sine of the critical angle is given by:
$ \sin \theta_{1C} = \frac{n_1}{n_2} $
$ \sin \theta_{2C} = \frac{n_1}{n_3} $
2. Difference Between Sines:
We are given that:
$ \sin \theta_{2C} - \sin \theta_{1C} = \frac{1}{2} $
Substituting the expressions for $ \sin \theta_{1C} $ and $ \sin \theta_{2C} $:
$ \frac{n_1}{n_3} - \frac{n_1}{n_2} = \frac{1}{2} $
3. Simplifying the Equation:
Factor out $ n_1 $:
$ n_1 \left( \frac{1}{n_3} - \frac{1}{n_2} \right) = \frac{1}{2} $
Simplify the terms inside the parentheses:
$ \frac{1}{n_3} - \frac{1}{n_2} = \frac{n_2 - n_3}{n_2 n_3} $
Thus, the equation becomes:
$ n_1 \cdot \frac{n_2 - n_3}{n_2 n_3} = \frac{1}{2} $
4. Substituting Given Values:
From the problem, we know:
$ n_1 \left( \frac{2}{5} - 1 \right) = \frac{n_3}{2} $
Simplify $ \frac{2}{5} - 1 $:
$ \frac{2}{5} - 1 = \frac{2}{5} - \frac{5}{5} = -\frac{3}{5} $
Substitute this back into the equation:
$ n_1 \cdot \left( -\frac{3}{5} \right) = \frac{n_3}{2} $
Solve for $ n_1 $:
$ n_1 = \frac{n_3}{2} \cdot \left( -\frac{5}{3} \right) = -\frac{5}{6} n_3 $
5. Ratio of Refractive Indices:
We now determine the ratio $ \frac{n_1}{n_2} $. From earlier, we know:
$ \frac{n_1}{n_2} = \frac{-5}{6} $
6. Inverse Sine Calculation:
Finally, the critical angle $ \theta_{1C} $ is given by:
$ \theta_{1C} = \sin^{-1} \left( \frac{n_1}{n_2} \right) $
Substitute $ \frac{n_1}{n_2} = \frac{-5}{6} $:
$ \theta_{1C} = \sin^{-1} \left( -\frac{5}{6} \right) $
Final Answer:
The critical angle $ \theta_{1C} $ is: $ \sin^{-1} \left( -\frac{5}{6} \right) $
A black body is at a temperature of 2880 K. The energy of radiation emitted by this body with wavelength between 499 nm and 500 nm is U1, between 999 nm and 1000 nm is U2 and between 1499 nm and 1500 nm is U3. The Wien's constant, b = 2.88×106 nm-K. Then,

What will be the equilibrium constant of the given reaction carried out in a \(5 \,L\) vessel and having equilibrium amounts of \(A_2\) and \(A\) as \(0.5\) mole and \(2 \times 10^{-6}\) mole respectively?
The reaction : \(A_2 \rightleftharpoons 2A\)