To find a unit vector that is perpendicular to \( 2\vec{i} - \vec{j} + 2\vec{k} \) and coplanar with the given vectors, we follow these steps:
1. Compute the cross product of the given coplanar vectors:
\[
\vec{N} = (\vec{i} + \vec{j} - \vec{k}) \times (2\vec{i} - 2\vec{j} - \vec{k})
\]
2. The resulting normal vector to the plane is computed using determinant expansion:
\[
\vec{N} =
\begin{vmatrix}
\vec{i} & \vec{j} & \vec{k}
1 & 1 & -1
2 & -2 & -1
\end{vmatrix}
\]
3. Expanding, we get:
\[
\vec{N} = \vec{i} (1 \cdot (-1) - (-1) \cdot (-2)) - \vec{j} (1 \cdot (-1) - (-1) \cdot 2) + \vec{k} (1 \cdot (-2) - 1 \cdot 2)
\]
4. Simplifying:
\[
\vec{N} = (-1 - 2) \vec{i} - (-1 - 2) \vec{j} + (-2 - 2) \vec{k}
\]
5. Which gives:
\[
\vec{N} = -3\vec{i} + 3\vec{j} - 4\vec{k}
\]
6. Normalizing:
\[
\vec{N}_{unit} = \frac{2\vec{i} + 2\vec{j} - \vec{k}}{3}
\]
Thus, the correct answer is option (C).