A two-level quantum system has energy eigenvalues
\( E_1 \) and \( E_2 \). A perturbing potential
\( H' = \lambda \Delta \sigma_x \) is introduced, where
\( \Delta \) is a constant having dimensions of energy,
\( \lambda \) is a small dimensionless parameter, and
\( \sigma_x = \begin{pmatrix} 0 & 1 \\ 1 & 0 \end{pmatrix} \).
The magnitudes of the first and the second order corrections to
\( E_1 \) due to \( H' \), respectively, are:
Step 1: The first-order energy correction in perturbation theory is given by the expectation value of the perturbing Hamiltonian in the unperturbed state. Since \( \sigma_x \) connects the two states, the first-order correction to the energy is zero.
Step 2: The second-order correction is non-zero and is given by the formula: \[ E_1^{(2)} = \frac{\lambda^2 \Delta^2}{|E_1 - E_2|} \] This is the second-order energy correction due to the perturbation \( H' = \lambda \Delta \sigma_x \).
| Column I | Column II |
(1)![]() | (P) Diamagnetic |
(2)![]() | (Q) Paramagnetic |
(3)![]() | (R) Ferromagnetic |
(4)![]() | (S) Antiferromagnetic |
Consider a two-level system with energy states \( +\epsilon \) and \( -\epsilon \). The number of particles at \( +\epsilon \) level is \( N+ \) and the number of particles at \( -\epsilon \) level is \( N- \). The total energy of the system is \( E \) and the total number of particles is \( N = N+ + N- \). In the thermodynamic limit, the inverse of the absolute temperature of the system is:
(Given: \( \ln N! \approx N \ln N - N \))