Step 1: Identify circuit condition.
Given that $|X_L| = |X_C| = 20\Omega$, the inductive and capacitive reactances cancel each other. Hence, the circuit operates at resonance.
Step 2: Calculate total impedance.
At resonance, the net reactance is zero and the impedance is purely resistive:
\[
Z = R = 10\Omega
\]
Step 3: Calculate circuit current.
\[
I = \frac{V_{\text{rms}}}{Z} = \frac{200}{10} = 20\text{ A}
\]
Step 4: Voltage across the capacitor.
\[
V_C = I \times X_C = 20 \times 20 = 400\text{ V}
\]
Step 5: Phase angle of capacitor voltage.
The voltage across a capacitor lags the current by $90^\circ$. Hence,
\[
V_C = 400 \angle -90^\circ \text{ V}
\]
Step 6: Final conclusion.
Therefore, the rms voltage across the capacitor is $400 \angle -90^\circ$ V.