Step 1: Understanding the formula.
The perimeter \( P \) of a sector is given by:
\[
P = 2r + \theta \cdot r
\]
where \( r \) is the radius and \( \theta \) is the angle in radians.
Step 2: Convert the angle to radians.
For an angle of \( 90° \), the angle in radians is:
\[
\theta = \frac{90°}{180°} \cdot \pi = \frac{\pi}{2}
\]
Step 3: Calculate the perimeter.
Substitute the values \( r = 14 \) cm and \( \theta = \frac{\pi}{2} \) into the perimeter formula:
\[
P = 2(14) + \frac{\pi}{2} \cdot 14 = 28 + 7\pi
\]
Step 4: Conclusion.
Therefore, the perimeter of the sector is \( 28 + 7\pi \) cm.
Final Answer: 28 + 7π.