



Given that material P decays into Q, and then Q decays into R, we need to determine the time-dependent mass of P, Q, and R.
1. Decay of P to Q: Let the initial mass of P be \( m_0 \). The mass of P at time \( t \) is given by the exponential decay equation: \[ m_P(t) = m_0 e^{-\lambda_1 t} \] where \( \lambda_1 \) is the decay constant for P. This describes how P decreases over time.
2. Decay of Q to R: The mass of Q at time \( t \) is determined by the difference between the mass of P that has decayed and the mass of Q that has decayed into R.
The mass of Q at any given time is given by: \[ m_Q(t) = \frac{\lambda_1}{\lambda_2 - \lambda_1} m_0 \left(e^{-\lambda_1 t} - e^{-\lambda_2 t}\right) \] where \( \lambda_2 \) is the decay constant for Q.
This equation represents how Q evolves as it decays from P to R.
3. Mass of R: The mass of R at time \( t \) is the remaining mass, which can be expressed as the sum of the mass lost from P and Q: \[ m_R(t) = m_0 - m_P(t) - m_Q(t) \] Substituting the expressions for \( m_P(t) \) and \( m_Q(t) \): \[ m_R(t) = m_0 \left(1 - e^{-\lambda_1 t} - \frac{\lambda_1}{\lambda_2 - \lambda_1} \left(e^{-\lambda_1 t} - e^{-\lambda_2 t}\right)\right) \] This shows how R increases as both P and Q decay.
The correct figure representing the time-dependent mass of P, Q, and R is (2), where:
- The mass of P decreases exponentially.
- The mass of Q initially increases and then decreases as it decays into R.
- The mass of R increases as Q decays.
Step 1: Understanding the problem.
We are given a radioactive material \( P \), which first decays into material \( Q \), and then \( Q \) decays into a non-radioactive material \( R \). We need to determine the correct graph that represents the time-dependent masses of \( P \), \( Q \), and \( R \).
Step 2: Analyze the decay process.
- The mass of \( P \) decreases over time as it decays into \( Q \). Therefore, the graph for \( P \) should show a decreasing function over time.
The mass of \( Q \) increases as \( P \) decays into \( Q \), then decreases as \( Q \) decays into \( R \). Therefore, the graph for \( Q \) should show an initial increase followed by a decrease.
The mass of \( R \) increases over time as \( Q \) decays into \( R \), so the graph for \( R \) should show a gradual increase.
Step 3: Identifying the correct graph.
Option 1: Does not show the correct decay behavior for \( P \), \( Q \), and \( R \).
Option 2: Correctly shows \( P \) decreasing, \( Q \) increasing and then decreasing, and \( R \) increasing. This matches the description of the decay process.
Option 3: Does not show the correct increase and decrease patterns for \( Q \) and \( R \).
Option 4: Shows the wrong patterns for the masses of \( P \), \( Q \), and \( R \).
Step 4: Conclusion.
The correct option is (2), as it represents the time-dependent masses of \( P \), \( Q \), and \( R \) correctly.
A black body is at a temperature of 2880 K. The energy of radiation emitted by this body with wavelength between 499 nm and 500 nm is U1, between 999 nm and 1000 nm is U2 and between 1499 nm and 1500 nm is U3. The Wien's constant, b = 2.88×106 nm-K. Then,

What will be the equilibrium constant of the given reaction carried out in a \(5 \,L\) vessel and having equilibrium amounts of \(A_2\) and \(A\) as \(0.5\) mole and \(2 \times 10^{-6}\) mole respectively?
The reaction : \(A_2 \rightleftharpoons 2A\)