The problem is asking for the probability of rolling exactly one '6' when rolling a fair dice three times. This is a binomial probability problem.
The probability of rolling a '6' on a fair die is \( \frac{1}{6} \), and the probability of not rolling a '6' is \( \frac{5}{6} \).
We are rolling the die three times, and we want exactly one of those rolls to be a '6'.
The binomial probability formula is given by:
\[
P(X = k) = \binom{n}{k} p^k (1-p)^{n-k}
\]
where:
\( n \) is the number of trials (3 rolls),
\( k \) is the number of successful outcomes (exactly one '6'),
\( p \) is the probability of success on a single trial (\( \frac{1}{6} \)).
Substituting the values:
\[
P({exactly one '6'}) = \binom{3}{1} \left( \frac{1}{6} \right)^1 \left( \frac{5}{6} \right)^2
\]
\[
= 3 \times \frac{1}{6} \times \frac{25}{36} = 3 \times \frac{25}{216} = \frac{75}{216}.
\]
Thus, the probability of rolling exactly one '6' is \( \frac{75}{216} \).
Therefore, the correct answer is \( \boxed{A} \).