Approach: The key insight is that milk is only ever removed, never added. So track milk through the operation and let the changed ratio pin down the total.
Step 1: Name the quantities.
Let initial milk \(= 5x\) L and water \(= 2x\) L, so total \(= 7x\) L.
Step 2: Remove 14 L of mixture.
The 14 L leaves in the 5:2 ratio, so milk removed \(= 14 \times \frac{5}{7} = 10\) L and water removed \(= 14 \times \frac{2}{7} = 4\) L.
Now milk \(= 5x - 10\), water \(= 2x - 4\).
Step 3: Add 14 L of water.
Milk is untouched: \(5x - 10\). Water becomes \((2x - 4) + 14 = 2x + 10\).
Step 4: Apply the new ratio 5 : 4.
\[ \frac{5x - 10}{2x + 10} = \frac{5}{4}. \]
Cross-multiply:
\[ 4(5x - 10) = 5(2x + 10) \implies 20x - 40 = 10x + 50 \implies 10x = 90 \implies x = 9. \]
Step 5: Total mixture.
\[ 7x = 7 \times 9 = 63 \text{ L}. \]
Check: milk \(= 45 - 10 = 35\), water \(= 18 + 10 = 28\), and \(35 : 28 = 5 : 4\). Correct.
Final Answer: \(\boxed{63\text{ L}}\). (Option 1)