There are 6 red balls, each of different size. So among red balls, only 1 is the smallest.
Probability that we pick a red ball = not relevant here — question says:
"A red ball is selected" → so event space is red balls only.
So, favorable = 1 (smallest red), total red balls = 6
\[
P = \frac{1}{6}
\boxed{\frac{1}{6}}
\]