Step 1: Use the relation between peak and RMS values.
For a sinusoidal waveform,
\[
V_{\mathrm{rms}}
=
\frac{V_{\mathrm{max}}}{\sqrt{2}}.
\]
Given,
\[
V_{\mathrm{max}}=141\,\mathrm{V}.
\]
Step 2: Calculate the RMS value.
\[
V_{\mathrm{rms}}
=
\frac{141}{\sqrt{2}}
\approx
\frac{141}{1.414}
\approx100\,\mathrm{V}.
\]
Hence,
\[
\boxed{100\,\mathrm{V}}
\]
Therefore,
\[
\boxed{(B)}
\]
is the correct answer.