Laboratory Preparation of Methane:
Methane (\(CH_4\)) is prepared in the laboratory by heating sodium acetate with soda lime (a mixture of NaOH and CaO).
\[
\text{CH}_3\text{COONa} + NaOH \rightarrow CH_4 + Na_2CO_3
\]
Reaction with Chlorine:
Methane reacts with chlorine in the presence of sunlight, leading to a substitution reaction:
\[
CH_4 + Cl_2 \xrightarrow{hv} CH_3Cl + HCl
\]
Further chlorination leads to the formation of dichloromethane, trichloromethane, and tetrachloromethane.
\[
CH_3Cl + Cl_2 \xrightarrow{hv} CH_2Cl_2 + HCl
\]