Let the mass of the fireman be \( m \), and let the tension in the rope be \( T \). As the fireman slides down with acceleration \( a \), we apply Newton’s second law:
\[
mg - T = ma \quad \Rightarrow \quad T = m(g - a)
\]
Given that the maximum breaking strength of the rope is \( \frac{2}{3} \) of the fireman's weight:
\[
T \leq \frac{2}{3}mg
\]
Substituting for \( T \):
\[
m(g - a) \leq \frac{2}{3}mg
\Rightarrow g - a \leq \frac{2}{3}g
\Rightarrow a \geq \frac{1}{3}g
\]
So, the minimum acceleration the fireman must slide down with to prevent the rope from breaking is \( \frac{1}{3}g \).