Question:

Why do Transition Metals act as good catalysts and form a large number of complex compounds?

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Key idea: Variable oxidation states + d-orbitals = catalysis and complex formation.
Updated On: Mar 22, 2026
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Solution and Explanation

Concept: Transition metals have unique electronic configurations and variable oxidation states, which make them suitable for catalysis and complex formation.
Answer:
Catalytic Activity:
  • Variable Oxidation States: Transition metals can easily change oxidation states, helping in redox reactions.
  • Formation of Intermediates: They form unstable intermediate compounds, lowering activation energy.
  • Surface Adsorption: Metals like Fe, Ni, and Pt adsorb reactants on their surface, facilitating reactions.
Formation of Complex Compounds:
  • Small Size and High Charge Density: Enables strong attraction with ligands.
  • Availability of d-Orbitals: Vacant d-orbitals allow coordinate bond formation.
  • Variable Oxidation States: Allows formation of different complexes.
Thus, the electronic structure and chemical properties of transition metals make them effective catalysts and capable of forming numerous complex compounds.
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