Question:

Which one of the following options is correct?
Red mud is generated in the production of:

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Red mud is the iron-rich, insoluble residue left over when bauxite is digested in sodium hydroxide during the Bayer process.
Updated On: Jul 28, 2026
  • Aluminium
  • Iron
  • Titanium
  • Copper
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The Correct Option is A

Solution and Explanation

Step 1: Recall where aluminium comes from.
Aluminium metal is extracted from its ore bauxite in two broad stages: first, the Bayer process purifies bauxite into alumina (\(Al_2O_3\)), and then the Hall-Heroult process electrolytically reduces alumina to metallic aluminium. Red mud is a byproduct of the first stage, the Bayer process.

Step 2: Recall the Bayer process itself.
In the Bayer process, crushed bauxite ore is digested in hot, concentrated sodium hydroxide (\(NaOH\)) solution under pressure. The aluminium-bearing minerals in the ore dissolve as sodium aluminate, while the impurities in the ore, mainly iron oxides, silica, titanium oxide, and other insoluble solids, do not dissolve and are filtered off as a solid residue.

Step 3: Identify red mud.
This insoluble residue is called red mud, and it gets its reddish-brown colour mainly from the iron oxide content left behind from the original bauxite ore. Red mud is produced in very large volumes (typically one to two tonnes of red mud per tonne of alumina produced) and is a well known environmental disposal challenge for the aluminium industry.

Step 4: Rule out the other metals.
(B) Iron: Iron is extracted from iron ore (hematite/magnetite) in a blast furnace, producing slag as its main waste, not red mud. Incorrect.
(C) Titanium: Titanium is extracted mainly from ilmenite or rutile by the Kroll process, which produces magnesium chloride as a byproduct, not red mud. Incorrect.
(D) Copper: Copper is extracted from sulfide ores mainly by smelting, producing slag and sulfur dioxide gas, not red mud. Incorrect.

Step 5: Final conclusion.
Red mud is specifically the insoluble bauxite residue from the Bayer process used to make alumina on the way to metallic aluminium.
\[ \boxed{\text{Aluminium}} \]
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