Step 1: Understanding electron configuration.
To determine the number of unpaired electrons, we need to look at the electron configurations of the ions:
- Cu\(^{2+}\) has the electron configuration [Ar] 3d\(^9\), which has one unpaired electron.
- Na\(^{+}\) has the electron configuration [Ne], which has no unpaired electrons.
- Cr\(^{3+}\) has the electron configuration [Ar] 3d\(^3\), which has three unpaired electrons.
- Fe\(^{3+}\) has the electron configuration [Ar] 3d\(^5\), which has five unpaired electrons.
Step 2: Conclusion.
The correct answer is (D) Fe\(^{3+}\), which has the maximum number of unpaired electrons.
| Group I | Group II |
| P) NaCl | 1) Coordination bond |
| Q) $H_2$ | 2) Polar covalent bond |
| R) $Pd-P$ bond in $Pd(PPh_3)_4 | 3) Covalent bond |
| S) $C-Cl$ bond in $CH_3Cl $ | 4) Ionic bond |

