A polymorph is a mineral that can crystallize in more than one form, having different crystal structures while maintaining the same chemical composition.
- Fluorite has multiple polymorphs such as cubic and octahedral forms.
- Pyrite crystallizes in one form, which is the cubic structure, so it does not have any polymorphs.
- Calcite has polymorphs like aragonite and vaterite, both being forms of calcium carbonate.
- Diamond, though a form of carbon, doesn't have any polymorphs as it has only one structure, making it a unique crystalline form of carbon.
Thus, the correct answer is option (A).
Final Answer:
\[
\boxed{\text{Fluorite}}
\]