Concept: A chelating ligand is a polydentate ligand that can bond to a single central metal atom through two or more donor atoms simultaneously, forming a ring structure (chelate ring).
Step 1: Identify the denticity of the options.
\( NH_3 \) (Ammonia): Unidentate (one donor N atom). \( H_2 O \) (Water): Unidentate (one donor O atom). \( Cl- \) (Chloride): Unidentate (one donor Cl atom). \( C_2 O_42- \) (Oxalate): Didentate (two donor O atoms).
Step 2: Determine the chelating agent.
Because the oxalate ion (\( C_2 O_42- \)) has two donor atoms that can coordinate to the same metal ion to form a five-membered ring, it is classified as a chelating ligand.
(i)[Ni(CN)₄]²⁻ and [Ni(CO)(_4)] have different structures, but do not differ in their magnetic behaviour. Explain.
(ii) Write the formula of Tetraamineaquachloridocobalt(III)chloride.
(i) Write two postulates of Werner's coordination theory.
(ii) Draw the geometrical isomers of [(NH_3)_3(NO_2)_3] and give their structures.