Step 1: Count atoms on each side.
LHS: Pb=1, N=2, O=6.
RHS: Pb=1, N=1 (in NO\textsubscript{2}), O=5 (1 in PbO, 2 in NO\textsubscript{2}, 2 in O\textsubscript{2}).
Step 2: Observation.
N and O counts differ, so the equation is not balanced. Others are balanced.
Step 3: Conclusion.
Thus option (4) is not balanced.