Step 1: Understanding the Concept:
The number of valence electrons is equal to the group number (for main group elements).
Aluminium (Al): Group 13 → 3 valence electrons.
Phosphorus (P): Group 15 → 5 valence electrons.
Sodium (Na): Group 1 → 1 valence electron.
Silicon (Si): Group 14 → 4 valence electrons.
Step 2: Detailed Explanation:
Among the given elements, phosphorus has the maximum number of valence electrons (5).
Step 3: Final Answer:
The element with the highest number of valence electrons is Phosphorus (P).