Step 1: Understand what “richest biodiversity” means.
Rich biodiversity refers to:
very high species richness,
large number of endemic species,
wide variety of ecosystems.
Step 2: Compare the given countries.
India: One of the 17 megadiverse countries, rich biodiversity.
South Africa: High biodiversity but geographically smaller.
Brazil: Contains the Amazon rainforest, the largest tropical rainforest in the world, and has the highest number of plant and animal species globally.
Russia: Very large area but comparatively lower species diversity due to cold climate.
Step 3: Identify the country with maximum biodiversity.
Brazil ranks first in the world in terms of overall biodiversity.
Hence, the correct answer is
\[
\boxed{\text{Brazil}}
\]