Concept:
Coal tar is separated into fractions by distillation. The heavy residue called pitch is widely used for paving and road surfacing.
Step 1:
Coal tar contains many hydrocarbons that are separated according to boiling range.
Step 2:
Light oil and middle oil are more volatile fractions used for chemicals and solvents.
Step 3:
Pitch is the thick black residue remaining after removal of lighter fractions.
Step 4:
Pitch has adhesive and waterproofing properties, making it suitable for road surfacing.
Step 5:
Therefore, the correct option is pitch.