Question:

When \(\mathrm{XO_2}\) is fused with an alkali metal hydroxide in presence of an oxidizing agent such as \(\mathrm{KNO_3}\); a dark green product is formed which disproportionates in acidic solution to afford a dark purple solution. X is :

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\(\mathrm{MnO_2}\) fused with KOH and \(\mathrm{KNO_3}\) gives green \(\mathrm{K_2MnO_4}\), which disproportionates to purple \(\mathrm{MnO_4^-}\).
Updated On: Nov 11, 2026
  • Ti
  • V
  • Cr
  • Mn
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The Correct Option is D

Solution and Explanation

\(\mathrm{MnO_2 + 2KOH + KNO_3 \rightarrow K_2MnO_4 + KNO_2 + H_2O}\): dark green potassium manganate.
In acidic solution: \(\mathrm{3MnO_4^{2-} + 4H^+ \rightarrow 2MnO_4^- + MnO_2 + 2H_2O}\), giving the dark purple permanganate ion.
So X = Mn.
Answer: (4) Mn
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